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  2. Green chemistry - Wikipedia

    en.wikipedia.org/wiki/Green_chemistry

    Green chemistry, similar to sustainable chemistry or circular chemistry, [1] is an area of chemistry and chemical engineering focused on the design of products and processes that minimize or eliminate the use and generation of hazardous substances. [2]

  3. Sodium bis (2-methoxyethoxy)aluminium hydride - Wikipedia

    en.wikipedia.org/wiki/Sodium_bis(2-methoxyethoxy...

    SMEAH in toluene under reflux has been used to reduce aliphatic p-toluenesulfonamides (TsNR 2) to the corresponding free amines and is one of the few reagents that can carry out this challenging reduction in general settings. Notably, LiAlH 4 does not reduce this functional group unless forcing conditions are used. [2]

  4. Reductive amination - Wikipedia

    en.wikipedia.org/wiki/Reductive_amination

    It is a common method to make amines and is widely used in green chemistry since it can be done catalytically in one-pot under mild conditions. In biochemistry, dehydrogenase enzymes use reductive amination to produce the amino acid glutamate. Additionally, there is ongoing research on alternative synthesis mechanisms with various metal ...

  5. Derivatization - Wikipedia

    en.wikipedia.org/wiki/Derivatization

    Derivatization is a technique used in chemistry which converts a chemical compound into a product (the reaction's derivate) of similar chemical structure, called a derivative. Generally, a specific functional group of the compound participates in the derivatization reaction and transforms the educt to a derivate of deviating reactivity ...

  6. Green solvent - Wikipedia

    en.wikipedia.org/wiki/Green_solvent

    Green solvents are environmentally friendly chemical solvents that are used as a part of green chemistry. They came to prominence in 2015, when the UN defined a new sustainability -focused development plan based on 17 sustainable development goals, recognizing the need for green chemistry and green solvents for a more sustainable future. [ 1 ]

  7. Indane - Wikipedia

    en.wikipedia.org/wiki/Indane

    Other derivatives can be obtained indirectly, e.g. the reaction of diethyl phthalate with ethyl acetate, using metallic sodium and ethanol as a catalyst. The reaction yields indanedione ethyl ester, which can react with the sodium ions yielding a salt. This can be reversed by adding an aqueous solution of hydrochloric acid.

  8. Birch reduction - Wikipedia

    en.wikipedia.org/wiki/Birch_reduction

    The Birch reduction is an organic reaction that is used to convert arenes to 1,4-cyclohexadienes.The reaction is named after the Australian chemist Arthur Birch and involves the organic reduction of aromatic rings in an amine solvent (traditionally liquid ammonia) with an alkali metal (traditionally sodium) and a proton source (traditionally an alcohol).

  9. Reduced derivative - Wikipedia

    en.wikipedia.org/wiki/Reduced_derivative

    In mathematics, the reduced derivative is a generalization of the notion of derivative that is well-suited to the study of functions of bounded variation. Although functions of bounded variation have derivatives in the sense of Radon measures, it is desirable to have a derivative that takes values in the same space as the functions themselves ...