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Because the molecule in its ground state has a non-zero spin magnetic moment, oxygen is paramagnetic; i.e., it can be attracted to the poles of a magnet. Thus, the Lewis structure O=O with all electrons in pairs does not accurately represent the nature of the bonding in molecular oxygen.
Liquid oxygen has a clear cyan color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. [2] Liquid oxygen has a density of 1.141 kg/L (1.141 g/ml), slightly denser than liquid water, and is cryogenic with a freezing point of 54.36 K (−218.79 °C; −361.82 °F) and a boiling point of 90.19 K (−182.96 °C; −297.33 °F) at 1 bar (14.5 psi).
Solid oxygen forms at normal atmospheric pressure at a temperature below 54.36 K (−218.79 °C, −361.82 °F). Solid oxygen O 2, like liquid oxygen, is a clear substance with a light sky-blue color caused by absorption in the red part of the visible light spectrum.
In nature, singlet oxygen is commonly formed from water during photosynthesis, using the energy of sunlight. [38] It is also produced in the troposphere by the photolysis of ozone by light of short wavelength [ 39 ] and by the immune system as a source of active oxygen. [ 40 ]
When orbital angular momentum contributions to the magnetic moment are small, as occurs for most organic radicals or for octahedral transition metal complexes with d 3 or high-spin d 5 configurations, the effective magnetic moment takes the form ( with g-factor g e = 2.0023... ≈ 2), (+) = (+), where N u is the number of unpaired electrons. In ...
It was proposed early in the 20th century. The MOT explains the paramagnetic nature of O 2, which valence bond theory cannot explain. In molecular orbital theory, electrons in a molecule are not assigned to individual chemical bonds between atoms, but are treated as moving under the influence of the atomic nuclei in the whole molecule. [1]
In a magnetic field the degeneracy of the levels is split into two levels with z projections of angular momenta +1ħ and −1ħ around the molecular axis. The magnetic transition between these levels gives rise to the g = 1 {\displaystyle g=1} EPR transition.
There are three known stable isotopes of oxygen (8 O): 16 O, 17 O, and 18 O. Radioactive isotopes ranging from 11 O to 28 O have also been characterized, all short-lived. The longest-lived radioisotope is 15