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Nitrogen triiodide is an inorganic compound with the formula N I 3. It is an extremely sensitive contact explosive : small quantities explode with a loud, sharp snap when touched even lightly, releasing a purple cloud of iodine vapor; it can even be detonated by alpha radiation .
The triiodide anion is easily polarised and in many salts, one I−I bond becomes shorter than the other. Only in combination with large cations, e.g. a quaternary ammonium such as [N(CH 3) 4] +, may the triiodide remain roughly symmetrical. [3] In solution phase, the bond lengths and angles of triiodide vary depending on the nature of solvent ...
(Nonetheless, nitrogen triiodide is named as an iodide as it is analogous to the other nitrogen trihalides.) [7] Given the large size of the iodide anion and iodine's weak oxidising power, high oxidation states are difficult to achieve in binary iodides, the maximum known being in the pentaiodides of niobium, tantalum, and protactinium. Iodides ...
Nitrogen triiodide atomic shape. The structures and bonds that make up a contact explosive contribute to its instability. Covalent compounds that have a large unequal sharing of electrons have the capability to fall apart very easily and explosively. Nitrogen triiodide is a perfect example of this property.
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Detonating 15 g of Nitrogen triiodide - This compound is created by mixing iodine with concentrated ammonia, it is a contact explosive which can be set off with the smallest shock. It is also the only reaction that we know of which can be set off by alpha radiation. Date: 30 April 2013: Source: 15g of Nitrogen Tri-Iodide: Author: Michael Bell
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