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Solid cobalt(II) cyanide is a coordination polymer consisting of cobalt ions linked by cyanide units in a cubic arrangement, each such cobalt atom having octahedral geometry, and an additional cobalt atom in half of the cubic cavities. [5] That is, the structure is actually Co[Co(CN) 3] 2 in a zeolite-like structure. It forms hydrates and other ...
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Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands. [1] Most are anions. Cyanide is a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions.
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For commercial applications, some effort is made to avoid halide impurities by using acetate salts of zinc: [5] [6] Zn(CH 3 COO) 2 + HCN → Zn(CN) 2 + 2 CH 3 COOH. Zinc cyanide is also produced as a byproduct of certain gold extraction methods. Procedures to isolate gold from aqueous gold cyanide sometimes call for the addition of zinc:
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Cobalt powder reacts with ammonia to form two kinds of nitrides, Co 2 N and Co 3 N. Cobalt reacts with phosphorus or arsenic to form Co 2 P, CoP, [2] CoP 2, [6] CoAs 2 and other substances. [2] The former three compounds are of interest as catalysts for water electrolysis .