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The calorific value Q of coal [kJ/kg] is the heat liberated by its complete combustion with oxygen. Q is a complex function of the elemental composition of the coal [citation needed]. Q can be determined experimentally using calorimeters. Dulong suggests the following approximate formula for Q when the oxygen content is less than 10%:
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The calorific value is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions .
A nutritional Calorie is equivalent to a thousand chemical or thermodynamic calories (abbreviated "cal" with a lower case "c") or one kilocalorie (kcal). Because food energy is commonly measured in Calories, the energy density of food is commonly called "caloric density". [ 7 ]
The heat content of sub-bituminous coals range from 8300 to 11,500 BTu/lb or 19.3 to 26.7 M J/kg. Their relatively low density and high water content renders some types of sub-bituminous coals susceptible to spontaneous combustion if not packed densely during storage in order to exclude free air flow.
The products from the air cycle contain non-calorific nitrogen and are exhausted out the stack while the products of the steam cycle are kept as blue water gas. This gas is composed almost entirely of CO and H 2, and burns with a pale blue flame similar to natural gas. BWG has a calorific value of 11 MJ/m 3 (300 BTU/cu ft).
Thus methane has an HHV (Higher heating value) of 55.50 MJ/kg, the highest value of common fuels. Diesel fuel has an HHV value of 44.80 MJ/kg and anthracite coal a value of 32.50 MJ/kg. Moisture and ash-free firewood has a lower value of 21.70 MJ/kg while dry peat has the lowest value of all common fuels of about 15.00 MJ/kg.
Thus anthracite has a calorific value of 32.5 MJ/kg compared with that of dry wood of about 21 MJ/kg. Lignite or brown coal is even worse with a heat of combustion of only 15 MJ/kg, owing to the presence of non-combustible impurities. Bituminous coal has a value lower than anthracite, but neither lignite nor bituminous coal are smokeless owing ...
The "grand calorie" (also "kilocalorie", "kilogram-calorie", or "food calorie"; "kcal" or "Cal") is 1000 cal, that is, exactly 4184 J. It was originally defined so that the heat capacity of 1 kg of water would be 1 kcal/°C. With these units of heat energy, the units of heat capacity are 1 cal/°C = 4.184 J/K ; 1 kcal/°C = 4184 J/K.