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Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
The Oceanic carbon cycle is a central process to the global carbon cycle and contains both inorganic carbon (carbon not associated with a living thing, such as carbon dioxide) and organic carbon (carbon that is, or has been, incorporated into a living thing). Part of the marine carbon cycle transforms carbon between non-living and living matter.
It constitutes around 38,000 Pg C [18] and includes dissolved carbon dioxide (CO 2), bicarbonate (HCO − 3), carbonate (CO 2− 3), and carbonic acid (H 2 C O 3). The equilibrium between carbonic acid and carbonate determines the pH of the seawater. Carbon dioxide dissolves easily in water and its solubility is inversely related to temperature.
The balance of these carbonate species (which ultimately affects the solubility of carbon dioxide), is dependent on factors such as pH, as shown in a Bjerrum plot.In seawater this is regulated by the charge balance of a number of positive (e.g. Na +, K +, Mg 2+, Ca 2+) and negative (e.g. CO 3 2− itself, Cl −, SO 4 2−, Br −) ions.
Relationship of phosphate to nitrate uptake for photosynthesis in various regions of the ocean. Note that nitrate is more often limiting than phosphate The Redfield ratio or Redfield stoichiometry is the consistent atomic ratio of carbon , nitrogen and phosphorus found in marine phytoplankton and throughout the deep oceans.
Between 1950 and 2020, the average pH of the ocean surface fell from approximately 8.15 to 8.05. [2] Carbon dioxide emissions from human activities are the primary cause of ocean acidification, with atmospheric carbon dioxide (CO 2) levels exceeding 422 ppm (as of 2024). [3] CO 2 from the atmosphere is absorbed by the oceans.
As the ocean acidifies, the increased uptake of CO 2 by seawater increases the concentration of hydrogen ions, which lowers the pH of the water. [14] This change in the chemical equilibrium of the inorganic carbon system reduces the concentration of these carbonate ions. This reduces the ability of these organisms to create their shells and ...
The impact of human activity on the chemistry of the Earth's oceans has increased over time, with pollution from industry and various land-use practices significantly affecting the oceans. Moreover, increasing levels of carbon dioxide in the Earth's atmosphere have led to ocean acidification, which has