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B-type chains, making half of the branches, have two branch points, and all chains have the same length. E. Meléndez-Hevia, R. Meléndez and E. I. Canela (2000) "Glycogen Structure: an Evolutionary View", pp. 319–326 in Technological and Medical Implications of Metabolic Control Analysis (ed. A. Cornish-Bowden and M. L. Cárdenas), Kluwer Academic Publishers, Dordrecht
Phosphorolysis is the cleavage of a compound in which inorganic phosphate is the attacking group. It is analogous to hydrolysis. [1]An example of this is glycogen breakdown by glycogen phosphorylase, which catalyzes attack by inorganic phosphate on the terminal glycosyl residue at the nonreducing end of a glycogen molecule.
Glycogen is analogous to starch, a glucose polymer in plants, and is sometimes referred to as animal starch, [16] having a similar structure to amylopectin but more extensively branched and compact than starch. Glycogen is a polymer of α(1→4) glycosidic bonds linked with α(1→6)-linked branches.
Homopolysaccharides are polysaccharides composed of a single type of sugar monomer. For example, cellulose is an unbranched homopolysaccharide made up of glucose monomers connected via beta-glycosidic linkages; glycogen is a branched form, where the glucose monomers are joined by alpha-glycosidic linkages.
Starch phosphorylase is a form of phosphorylase similar to glycogen phosphorylase, except that it acts upon starch instead of glycogen.. The plant alpha-glucan phosphorylase, commonly called starch phosphorylase (EC 2.4.1.1), is largely known for the phosphorolytic degradation of starch.
The overall reaction for the breakdown of glycogen to glucose-1-phosphate is: [1] glycogen (n residues) + P i ⇌ glycogen (n-1 residues) + glucose-1-phosphate. Here, glycogen phosphorylase cleaves the bond linking a terminal glucose residue to a glycogen branch by substitution of a phosphoryl group for the α[1→4] linkage. [1]
Liver glycogen stores serve as a store of glucose for use throughout the body, particularly the central nervous system. [4] The human brain consumes approximately 60% of blood glucose in fasted, sedentary individuals. [4] Glycogen is an analogue of starch, a glucose polymer that functions as energy storage in plants.
Carbohydrate synthesis is a sub-field of organic chemistry concerned with generating complex carbohydrate structures from simple units (monosaccharides). The generation of carbohydrate structures usually involves linking monosaccharides or oligosaccharides through glycosidic bonds, a process called glycosylation.