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Anhydrous ammonia corrodes copper- and zinc-containing alloys, which makes brass fittings not appropriate for handling the gas. Liquid ammonia can also attack rubber and certain plastics. Ammonia reacts violently with the halogens. Nitrogen triiodide, a primary high explosive, is formed when ammonia comes in contact with iodine.
As of 2018, the Haber process produces 230 million tonnes of anhydrous ammonia per year. [69] The ammonia is used mainly as a nitrogen fertilizer as ammonia itself, in the form of ammonium nitrate, and as urea. The Haber process consumes 3–5% of the world's natural gas production (around 1–2% of the world's energy supply).
Ammonia electrolysis may require much less thermodynamic energy than water electrolysis (only 0.06 V in alkaline media). [23] Another option for recovering ammonia from wastewater is to use the mechanics of the ammonia-water thermal absorption cycle. [24] [25] Ammonia can thus be recovered either as a liquid or as ammonium hydroxide. The ...
Several nitrogen-bearing reductants are used in SCR applications including anhydrous ammonia, aqueous ammonia or dissolved urea. All those three reductants are widely available in large quantities. Anhydrous ammonia can be stored as a liquid at approximately 10 bar in steel tanks.
Ammonium nitrate is an important fertilizer with NPK rating 34-0-0 (34% nitrogen). [17] It is less concentrated than urea (46-0-0), giving ammonium nitrate a slight transportation disadvantage. Ammonium nitrate's advantage over urea is that it is more stable and does not rapidly lose nitrogen to the atmosphere.
The table above gives properties of the vapor–liquid equilibrium of anhydrous ammonia at various temperatures. The second column is vapor pressure in kPa. The third column is the density of the liquid phase. The fourth column is the density of the vapor. The fifth column is the heat of vaporization needed to convert one gram of liquid to vapor.
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Liquid nitrogen is a compact and readily transported source of dry nitrogen gas, as it does not require pressurization. Further, its ability to maintain temperatures far below the freezing point of water, specific heat of 1040 J ⋅kg −1 ⋅K −1 and heat of vaporization of 200 kJ⋅kg −1 makes it extremely useful in a wide range of ...