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  2. Atmospheric methane - Wikipedia

    en.wikipedia.org/wiki/Atmospheric_methane

    An increase in methane emissions greater than the regeneration rate of OH radicals would reduce their concentrations and so increase methane's mean atmospheric lifetime. [68] [70] The reaction of methane and chlorine atoms acts as a primary sink of Cl atoms and is a primary source of hydrochloric acid (HCl) in the stratosphere. [71] CH 4 + Cl ...

  3. Free-radical halogenation - Wikipedia

    en.wikipedia.org/wiki/Free-radical_halogenation

    Two free radicals (chlorine and chlorine, chlorine and methyl, or methyl and methyl) combine: Methane chlorination: termination The last possibility generates in an impurity in the final mixture (notably, an organic molecule with a longer carbon chain than the reactants). The net reaction is: Methane chlorination overall reaction

  4. Methane - Wikipedia

    en.wikipedia.org/wiki/Methane

    Similar reactions can occur on the halogenated product, leading to replacement of additional hydrogen atoms by halogen atoms with dihalomethane, trihalomethane, and ultimately, tetrahalomethane structures, depending upon reaction conditions and the halogen-to-methane ratio. This reaction is commonly used with chlorine to produce dichloromethane ...

  5. Dichloromethane - Wikipedia

    en.wikipedia.org/wiki/Dichloromethane

    DCM is produced by treating either chloromethane or methane with chlorine gas at 400–500 °C. At these temperatures, both methane and chloromethane undergo a series of reactions producing progressively more chlorinated products. In this way, an estimated 400,000 tons were produced in the US, Europe, and Japan in 1993. [12] CH 4 + Cl 2 → CH ...

  6. Chloromethane - Wikipedia

    en.wikipedia.org/wiki/Chloromethane

    A smaller amount of chloromethane is produced by treating a mixture of methane with chlorine at elevated temperatures. This method, however, also produces more highly chlorinated compounds such as dichloromethane, chloroform, and carbon tetrachloride. For this reason, methane chlorination is usually only practiced when these other products are ...

  7. Photochlorination - Wikipedia

    en.wikipedia.org/wiki/Photochlorination

    Photochlorination is a chlorination reaction that is initiated by light. Usually a C-H bond is converted to a C-Cl bond. Photochlorination is carried out on an industrial scale. The process is exothermic and proceeds as a chain reaction initiated by the homolytic cleavage of molecular chlorine into chlorine radicals by ultraviolet radiation.

  8. Trihalomethane - Wikipedia

    en.wikipedia.org/wiki/Trihalomethane

    Trihalomethane. In chemistry, trihalomethanes (THM s) are chemical compounds in which three of the four hydrogen atoms of methane (CH4) are replaced by halogen atoms. Trihalomethanes with all the same halogen atoms are called haloforms. Many trihalomethanes find uses in industry as solvents or refrigerants.

  9. Carbon tetrachloride - Wikipedia

    en.wikipedia.org/wiki/Carbon_tetrachloride

    Carbon tetrachloride, also known by many other names (such as carbon tet for short and tetrachloromethane, also recognised by the IUPAC), is a chemical compound with the chemical formula CCl 4. It is a non-flammable, dense, colourless liquid with a "sweet" chloroform -like odour that can be detected at low levels.