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The infrared spectrum of liquid water is dominated by the intense absorption due to the fundamental O-H stretching vibrations. Because of the high intensity, very short path lengths, usually less than 50 μm, are needed to record the spectra of aqueous solutions.
However, water and ice absorb in infrared and close the infrared atmospheric window, thereby contributing to the greenhouse effect. The absorption spectrum of pure water is used in numerous applications, including light scattering and absorption by ice crystals and cloud water droplets , theories of the rainbow , determination of the single ...
Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify ...
Infrared can also be used to detect protostars before they begin to emit visible light. Stars emit a smaller portion of their energy in the infrared spectrum, so nearby cool objects such as planets can be more readily detected. (In the visible light spectrum, the glare from the star will drown out the reflected light from a planet.)
Fourier transform infrared spectroscopy (FTIR) [1] is a technique used to obtain an infrared spectrum of absorption or emission of a solid, liquid, or gas. An FTIR spectrometer simultaneously collects high-resolution spectral data over a wide spectral range.
Although water is nearly transparent in the range of visible light, it becomes absorbing over the near-infrared region. Water is a critical component since its concentration is high in human tissue. The absorption spectrum of water in the range from 250 to 1000 nm is shown in Figure 2.
Water vapor absorbing these wavelengths of IR energy is mainly attributed to water being a polar molecule. Water's polarity allows it to absorb and release radiation at far, near and mid-infrared wavelengths. [6] The polarity also largely impacts how water interacts with nature, for it allows complexes of water, such as the water dimer. [6]
The visible and near-infrared (VNIR) portion of the electromagnetic spectrum has wavelengths between approximately 400 and 1100 nanometers (nm). [1] It combines the full visible spectrum with an adjacent portion of the infrared spectrum up to the water absorption band between 1400 and 1500 nm.