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Unit cell definition using parallelepiped with lengths a, b, c and angles between the sides given by α, β, γ [1]. A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal.
The crystal structure consists of the same group of atoms, the basis, positioned around each and every lattice point. This group of atoms therefore repeats indefinitely in three dimensions according to the arrangement of one of the Bravais lattices.
The diamond crystal structure belongs to the face-centered cubic lattice, with a repeated two-atom pattern. In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices.
For example, a crystal, viewed as a lattice with a single kind of atom located at every lattice point (the simplest basis form), may also be viewed as a lattice with a basis of two atoms. In this case, a primitive unit cell is a unit cell having only one lattice point in the first way of describing the crystal in order to ensure the smallest ...
The crystal structure can be described as a Bravais lattice with a group of atoms, called the basis, placed at every lattice point; that is, [crystal structure] = [lattice] [basis]. If the lattice is infinite and completely regular, the system is a perfect crystal .
This is based on the fact that a reciprocal lattice vector (the vector indicating a reciprocal lattice point from the reciprocal lattice origin) is the wavevector of a plane wave in the Fourier series of a spatial function (e.g., electronic density function) which periodicity follows the original Bravais lattice, so wavefronts of the plane wave ...
Similar to the ideal hcp structure, the perfect dhcp structure should have a lattice parameter ratio of = In the real dhcp structures of 5 lanthanides (including β-Ce) / variates between 1.596 (Pm) and 1.6128 (Nd). For the four known actinides dhcp lattices the corresponding number vary between 1.620 (Bk) and 1.625 (Cf).
At the stability limit the cation is touching all the anions and the anions are just touching at their edges. For radius ratios greater than the critical ratius ratio, the structure is expected to be stable. The rule is not obeyed for all compounds. By one estimate, the crystal structure can only be guessed about 2/3 of the time. [3]