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Electroless nickel-boron plating developed as a variant of the similar nickel-phosphorus process, discovered accidentally by Charles Adolphe Wurtz in 1844. [2]In 1969, Harold Edward Bellis from DuPont filed a patent for a general class of electroless plating processes using sodium borohydride, dimethylamine borane, or sodium hypophosphite, in the presence of thallium salts, thus producing a ...
Boriding, also called boronizing, is the process by which boron is added to a metal or alloy.It is a type of surface hardening.In this process boron atoms are diffused into the surface of a metal component.
Dinickel boride is a chemical compound of nickel and boron with formula Ni 2 B. [1] [2] It is one of the borides of nickel.The formula "Ni2 B" and the name "nickel boride" are often used for a nickel-boron catalyst obtained by reacting nickel salts with sodium borohydride.
Nickel boride is the common name of materials composed chiefly of the elements nickel and boron that are widely used as catalysts in organic chemistry. [1] [2] Their approximate chemical composition is Ni 2.5 B, [3] and they are often incorrectly denoted "Ni 2 B" in organic chemistry publications.
A similar process uses a borohydride reducing agent, yielding a nickel-boron coating instead. Unlike electroplating , processes in general do not require passing an electric current through the bath and the substrate; the reduction of the metal cations in solution to metallic is achieved by purely chemical means, through an autocatalytic reaction.
The borides can be classified loosely as boron rich or metal rich, for example the compound YB 66 at one extreme through to Nd 2 Fe 14 B at the other. The generally accepted definition is that if the ratio of boron atoms to metal atoms is 4:1 or more, the compound is boron rich; if it is less, then it is metal rich.
The elements in group 13 are also capable of forming stable compounds with the halogens, usually with the formula MX 3 (where M is a boron-group element and X is a halogen.) [14] Fluorine, the first halogen, is able to form stable compounds with every element that has been tested (except neon and helium), [15] and the boron group is no exception.
Outgassing can be lowered with suitable (e.g. nickel) plating. It has high permeability to hydrogen and tendency to rust. For use it should be thoroughly degassed in vacuum. Aluminium and aluminium alloys are another class of frequently used materials.