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The kinetic theory of gases deals not only with gases in thermodynamic equilibrium, but also very importantly with gases not in thermodynamic equilibrium. This means using Kinetic Theory to consider what are known as "transport properties", such as viscosity, thermal conductivity, mass diffusivity and thermal diffusion.
Building on his theory of the mechanical explanation of gravity, he was the first to develop the kinetic theory, independently of earlier and equally neglected partial accounts by Daniel Bernoulli and John Herapath. He published it, at his own expense, in his book Thoughts on the Mental Functions (1843).
Perhaps the greatest success of the kinetic theory of gases, as it came to be called, was the discovery that for gases, the temperature as measured on the Kelvin (absolute) temperature scale is directly proportional to the average kinetic energy of the gas molecules. Graham's law for diffusion could thus be understood as a consequence of the ...
From the kinetic theory of gases, [20] thermal conductivity of principal carrier i (p, e, f and ph) is =,, where n i is the carrier density and the heat capacity is per carrier, u i is the carrier speed and λ i is the mean free path (distance traveled by carrier before an scattering event). Thus, the larger the carrier density, heat capacity ...
Note that different definitions of the molecular diameter, as well as different assumptions about the value of atmospheric pressure (100 vs 101.3 kPa) and room temperature (293.17 K vs 296.15 K or even 300 K) can lead to slightly different values of the mean free path.
Kinetic theory may refer to: Kinetic theory of matter: A general account of the properties of matter, including solids liquids and gases, based around the idea that heat or temperature is a manifestation of atoms and molecules in constant agitation. Kinetic theory of gases, an account of gas properties in terms of motion and interaction of ...
At the molecular level, gas dynamics is a study of the kinetic theory of gases, often leading to the study of gas diffusion, statistical mechanics, chemical thermodynamics and non-equilibrium thermodynamics. [2] Gas dynamics is synonymous with aerodynamics when the gas field is air and the subject of study is flight.
Effusion from an equilibrated container into outside vacuum can be calculated based on kinetic theory. [2] The number of atomic or molecular collisions with a wall of a container per unit area per unit time (impingement rate) is given by: =. assuming mean free path is much greater than pinhole diameter and the gas can be treated as an ideal gas.