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4-Carboxybenzaldehyde (CBA) is an organic compound with the formula OCHC 6 H 4 CO 2 H. It consists of a benzene ring substituted with both an aldehyde and a carboxylic acid, with these functional groups on opposite corners of the ring. This compound is formed in 0.5% yield as a byproduct in the production terephthalic acid from p-xylene. Since ...
Oil of tartar – concentrated potassium carbonate, K 2 CO 3 solution; Oil of tartar per deliquium – potassium carbonate dissolved in the water which its extracts from the air. Oil of vitriol/spirit of vitriol – sulfuric acid, a weak version can be formed by heating green vitriol and blue vitriol. H 2 SO 4
Potassium nitrate can be made by combining ammonium nitrate and potassium hydroxide. NH 4 NO 3 + KOH → NH 3 + KNO 3 + H 2 O. An alternative way of producing potassium nitrate without a by-product of ammonia is to combine ammonium nitrate, found in instant ice packs, [30] and potassium chloride, easily obtained as a sodium-free salt substitute.
In a laboratory procedure, the oxidation of naphthalene with alkaline potassium permanganate is given, which, however, yields only a yield of 39% 2-carboxybenzaldehyde. [9] Also the oxidation of naphthalene with ozone to 2-formylbenzoic acid offers no significant advantages. [10] Synthese von 2-Carboxybenzaldehyd aus Naphthalin
4-Nitrobenzoic acid is prepared by oxidation of 4-nitrotoluene using oxygen or dichromate as oxidants. [7] Alternatively, it has been prepared by nitration of polystyrene followed by oxidation of the alkyl substituent. This method proceeds with improved para/ortho selectivity owing to the steric protection of the ortho positions by the polymer ...
It also can be prepared by treating benzaldehyde under nitration conditions, a process that initially converts the aldehyde to the acid. 4-Nitrobenzoic acid is a precursor to 4-aminobenzoic acid, which is in turn used to prepare the anesthetic procaine. 4-Nitrobenzoic acid is prepared by oxidation of 4-nitrotoluene.
Dehydration by means of strong acid gives 3-Butylisocarbostyril [132-90-1] (8). Phosphorus oxychloride converts the oxygen function to the corresponding chloride via the enol forms 3-butyl-1-chloroisoquinoline [87-06-9] (9). Displacement of halogen with the sodium salt from 2-dimethylaminoethanol (10) affords dimethisoquin (11).
Potassium benzoate (E212), the potassium salt of benzoic acid, is a food preservative that inhibits the growth of mold, yeast and some bacteria. It works best in low- pH products, below 4.5, where it exists as benzoic acid.