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Hypophosphoric acid can be prepared by the reaction of red phosphorus with sodium chlorite at room temperature. [2]2 P + 2 NaClO 2 + 2 H 2 O → Na 2 H 2 P 2 O 6 + 2 HCl. A mixture of hypophosphoric acid, phosphorous acid (H 3 PO 3) and phosphoric acid (H 3 PO 4) is produced when white phosphorus oxidises in air when partially immersed in water.
A general formula for such cyclic compounds is [HPO 3] x where x = number of phosphoric units in the molecule. When metaphosphoric acids lose their hydrogens as H +, cyclic anions called metaphosphates are formed. An example of a compound with such an anion is sodium hexametaphosphate (Na 6 P 6 O 18), used as a sequestrant and a food additive.
It is a colorless low-melting compound, which is soluble in water, dioxane and alcohols. The formula for this acid is generally written H 3 PO 2, but a more descriptive presentation is HOP(O)H 2, which highlights its monoprotic character. Salts derived from this acid are called hypophosphites. [3]
In chemistry, phosphorus oxoacid (or phosphorus acid) is a generic name for any acid whose molecule consists of atoms of phosphorus, oxygen, and hydrogen. [1] There is a potentially infinite number of such compounds. Some of them are unstable and have not been isolated, but the derived anions and organic groups are present in stable salts and ...
The phosphate ion has a molar mass of 94.97 g/mol, and consists of a central phosphorus atom surrounded by four oxygen atoms in a tetrahedral arrangement. It is the conjugate base of the hydrogen phosphate ion H(PO 4) 2−, which in turn is the conjugate base of the dihydrogen phosphate ion H 2 (PO 4) −
The name "orthophosphoric acid" can be used to distinguish this specific acid from other "phosphoric acids", such as pyrophosphoric acid. Nevertheless, the term "phosphoric acid" often means this specific compound; and that is the current IUPAC nomenclature .
Other important organic compounds that contain oxygen are: glycerol, formaldehyde, glutaraldehyde, citric acid, acetic anhydride, acetamide, etc. Epoxides are ethers in which the oxygen atom is part of a ring of three atoms. Oxygen reacts spontaneously with many organic compounds at or below room temperature in a process called autoxidation. [7]
Phosphorus trichloride is an inorganic compound with the chemical formula PCl 3. A colorless liquid when pure, it is an important industrial chemical, being used for the manufacture of phosphites and other organophosphorus compounds. It is toxic and reacts readily with water to release hydrogen chloride.