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The first batches of Araldite epoxy resins, for which the brand is best known, were made in Duxford, England in 1950. [1] Araldite adhesive sets by the interaction of an epoxy resin with a hardener. Mixing an epoxy resin and hardener together starts a chemical reaction that produces heat – an exothermic reaction. [2]
The epoxy value is defined as the number of moles of epoxy group per 100g resin. So as an example using an epoxy resin with molar mass of 382 and that has 2 moles of epoxy groups per mole of resin, the EEW = 382/2 = 191, and the epoxy value is calculated as follows: 100/191 = 0.53 (i.e. the epoxy value of the resin is 0.53). [6]
The other production route for epoxy resins is the conversion of aliphatic or cycloaliphatic alkenes with peracids: [13] [14] In contrast to glycidyl-based epoxy resins, this production of such epoxy monomers does not require an acidic hydrogen atom but an aliphatic double bond.
The mixture sets in 4-6 hours and fully cures in up to 15 hours. It can be used as an adhesive, laminate, plug, filler, sealant, or electrical insulator and can be drilled, ground, tapped, machined, sanded, and painted when cured. J-B Kwik is a faster-curing two-part epoxy with medium-temperature resistance up to 300 °F (149 °C).
[12] [13] From the 1990s onward, concern has been raised over the use of BADGE-based epoxy resins in the lining of some cans for foodstuffs, with the chemical being found to leach into foods. [ 12 ] [ 14 ] Bisphenol A Diglycidyl ether-based epoxy coatings are extensively used for coating the inside of cans which come into contact with food and ...
The chemistry of the resin (for example an epoxy resin would use an epoxy reactive diluent) [4] The flexibility of the cured layer; The volatility; The environmental compatibility. [5] Reactive diluents used are low-viscosity, mono-, bi- or polyfunctional monomers or oligomers. In general, several different monomers are combined so that one ...