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Sodium aluminate is an inorganic chemical that is used as an effective source of aluminium hydroxide for many industrial and technical applications. Pure sodium aluminate ( anhydrous ) is a white crystalline solid having a formula variously given as NaAlO 2 , NaAl(OH) 4 ( hydrated ), [ 3 ] Na 2 O·Al 2 O 3 , or Na 2 Al 2 O 4 .
Aluminium oxide is an amphoteric substance, meaning it can react with both acids and bases, such as hydrofluoric acid and sodium hydroxide, acting as an acid with a base and a base with an acid, neutralising the other and producing a salt. Al 2 O 3 + 6 HF → 2 AlF 3 + 3 H 2 O Al 2 O 3 + 2 NaOH + 3 H 2 O → 2 NaAl(OH) 4 (sodium aluminate)
The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer.Bauxite, the most important ore of aluminium, contains only 30–60% aluminium oxide (Al 2 O 3), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
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A number of aluminate oxyanions are known: The simplest is the approximately tetrahedral AlO 5− 4 found in the compound Na 5 AlO 4, [2] framework AlO − 2 ions in anhydrous sodium aluminate NaAlO 2 [3] and monocalcium aluminate, CaAl 2 O 4 made up of corner-sharing {AlO 4} tetrahedra. [4] A ring anion, the cyclic Al 6 O 18−
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Cryolite (Na 3 Al F 6, sodium hexafluoroaluminate) is a rare mineral identified with the once-large deposit at Ivittuut on the west coast of Greenland, mined commercially until 1987. [8] It is used in the reduction ("smelting") of aluminium, in pest control, and as a dye.
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