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Download as PDF; Printable version ... This page provides supplementary chemical data on benzoyl peroxide. ... the Creative Commons Attribution-ShareAlike 4.0 License
Benzoyl peroxide is a chemical compound (specifically, an organic peroxide) with structural formula (C 6 H 5 −C(=O)O−) 2, often abbreviated as (BzO) 2. In terms of its structure, the molecule can be described as two benzoyl ( C 6 H 5 −C(=O)− , Bz) groups connected by a peroxide ( −O−O− ).
Benzoyl peroxide and hydrogen peroxide are used as bleaching and "maturing" agents for treating flour to make its grain release gluten more easily; the alternative is letting the flour slowly oxidize by air, which is too slow for the industrialized era. Benzoyl peroxide is an effective topical medication for treating most forms of acne.
Benzoyl peroxide, much like azobisisobutyronitrile, is a white powder used as a photoinitiator in various commercial and industrial processes, including plastics production. Unlike AIBN, however, benzoyl peroxide produces oxygen gas upon decomposing, giving this compound a host of medical uses as well.
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A standard procedure for the preparation of peresters is the acylation of tert-butyl hydroperoxide with benzoyl chloride. [6] In the reaction a large excess of tert-butyl hydroperoxide is used and the hydrogen chloride formed is removed in vacuo whereby a virtually quantitative yield is obtained.
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