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The Wijs solution, iodine monochloride dissolved in acetic acid, is used to determine the iodine value of a substance. It can also be used to prepare iodates, by reaction with a chlorate. Chlorine is released as a byproduct. Iodine monochloride is a Lewis acid that forms 1:1 adducts with Lewis bases such as dimethylacetamide and benzene.
In iodane chemistry, carbon is considered more electronegative than iodine, despite the Pauling electronegativities of those respective atoms. [2] Thus iodobenzene (C 6 H 5 I) is an iodine(I) compound, (dichloroiodo)benzene (C 6 H 5 ICl 2) and iodosobenzene (C 6 H 5 IO) iodine(III) compounds, and iodoxybenzene (C 6 H 5 IO 2) an iodine(V) compound.
Iodine trichloride, which exists in the solid state as the planar dimer I 2 Cl 6, is a bright yellow solid, synthesised by reacting iodine with liquid chlorine at −80 °C; caution is necessary during purification because it easily dissociates to iodine monochloride and chlorine and hence can act as a strong chlorinating agent.
Few organoiodine compounds are important industrially, at least in terms of large scale production. Iodide-containing intermediates are common in organic synthesis on the laboratory scale because of the easy formation and cleavage of the C–I bond. But the same lability of the C-I bond limits the applications of organoiodine compounds as drugs.
This is an accepted version of this page This is the latest accepted revision, reviewed on 25 February 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Iodine chloride may refer to: Iodine monochloride, ICl; Iodine dichloride, ICl 2 ...
The crystal structure of iodine monochloride consists of puckered zig-zag chains, with strong interactions between the chains. Astatine monochloride [ 7 ] (AtCl) is made either by the direct combination of gas-phase astatine with chlorine or by the sequential addition of astatine and dichromate ion to an acidic chloride solution.