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Sodium hydroxide, also known as lye and caustic soda, [1] [2] is an inorganic compound with the formula NaOH.It is a white solid ionic compound consisting of sodium cations Na + and hydroxide anions OH −.
The Parikh–Doering oxidation is an oxidation reaction that transforms primary and secondary alcohols into aldehydes and ketones, respectively. [1] The procedure uses dimethyl sulfoxide (DMSO) as the oxidant and the solvent, activated by the sulfur trioxide pyridine complex (SO 3 •C 5 H 5 N) in the presence of triethylamine or diisopropylethylamine as base.
4 NaClO + Na 2 S 2 O 3 + 2 NaOH → 4 NaCl + 2 Na 2 SO 4 + H 2 O. Similarly, sodium thiosulfate reacts with bromine, removing the free bromine from the solution. Solutions of sodium thiosulfate are commonly used as a precaution in chemistry laboratories when working with bromine and for the safe disposal of bromine, iodine, or other strong ...
The elementary reaction responsible for water quantification in the Karl Fischer titration is oxidation of sulfur dioxide (SO 2) with iodine: . H 2 O + SO 2 + I 2 → SO 3 + 2 HI. This elementary reaction consumes exactly one molar equivalent of water vs. iodine.
The molecule SO 3 is trigonal planar.As predicted by VSEPR theory, its structure belongs to the D 3h point group.The sulfur atom has an oxidation state of +6 and may be assigned a formal charge value as low as 0 (if all three sulfur-oxygen bonds are assumed to be double bonds) or as high as +2 (if the Octet Rule is assumed). [7]
Sodium sulfite (sodium sulphite) is the inorganic compound with the chemical formula Na 2 SO 3.A white, water-soluble solid, it is used commercially as an antioxidant and preservative.
2 NaOH(aq) + H 2 SO 4 (aq) → Na 2 SO 4 (aq) + 2 H 2 O(l) ΔH = -112.5 kJ (highly exothermic) In the laboratory it can also be synthesized from the reaction between sodium bicarbonate and magnesium sulfate, by precipitating magnesium carbonate. 2 NaHCO 3 + MgSO 4 → Na 2 SO 4 + MgCO 3 + CO 2 + H 2 O
In organic chemistry, the Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol (−OH) is oxidized to an aldehyde (−CH=O) or ketone (>C=O) using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine.