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The boron atom in BH 3 has 6 valence electrons. Consequently, it is a strong Lewis acid and reacts with any Lewis base ('L' in equation below) to form an adduct: [7] BH 3 + L → L—BH 3. in which the base donates its lone pair, forming a dative covalent bond. Such compounds are thermodynamically stable, but may be easily oxidised in air.
[3] Boranes are chemical compounds of boron and hydrogen, with the generic formula of B x H y. These compounds do not occur in nature. Many of the boranes readily oxidise on contact with air, some violently. The parent member BH 3 is called borane, but it is known only in the gaseous state, and dimerises to form diborane, B 2 H 6. The larger ...
A borane is a compound with the formula BR x H y although examples include multi-boron derivatives. A large family of boron hydride clusters is also known. In addition to some applications in organic chemistry , the boranes have attracted much attention as they exhibit structures and bonding that differs strongly from the patterns seen in ...
The great variety of boranes show a huge covalent cluster chemistry, but the heavier group 13 hydrides do not. Despite their formulae, however, they tend to form polymers. Alane(aluminum trihydride) is a strong reducing agent with octahedrally coordinated aluminium atom
The cyclic compound borepin has been isolated and is aromatic. Boron-boron multiple bonds are rare, although doubly-bonded dianions have been known since the 1990s. [20] Neutral analogues use NHC adducts, such as the following diborane(2) derivative: [21] [22] Each boron atom has an attached proton and is coordinated to a NHC carbene. [23] [24]
Boron hydride clusters are compounds with the formula B x H y or related anions, where x ≥ 3. Many such cluster compounds are known. Common examples are those with 5, 10, and 12 boron atoms. Although they have few practical applications, the borane hydride clusters exhibit structures and bonding that differs strongly from the patterns seen in ...
Ammonia borane (also systematically named ammoniotrihydroborate [citation needed]), also called borazane, is the chemical compound with the formula H 3 NBH 3.The colourless or white solid is the simplest molecular boron-nitrogen-hydride compound.
Like other boron hydride clusters, the structure of tetraborane involves multicenter bonding, with hydrogen bridges or protonated double bonds.According to its formula, B 4 H 10, it is classified as an arachno-cluster and has a butterfly geometry, which can be rationalized by Wade's rules. [5]