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In the 19th century, German chemist and physicist Julius von Mayer derived a relation between the molar heat capacity at constant pressure and the molar heat capacity at constant volume for an ideal gas.
This is a derivation to obtain an expression for for an ideal gas. An ideal gas has the equation of state: = where P = pressure V = volume n = number of moles R = universal gas constant T = temperature. The ideal gas equation of state can be arranged to give:
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
For a gas that is a mixture of two or more pure gases (air or natural gas, for example), the gas composition must be known before compressibility can be calculated. Alternatively, the compressibility factor for specific gases can be read from generalized compressibility charts [ 1 ] that plot Z {\displaystyle Z} as a function of pressure at ...
where F is the gravitational force acting between two objects, m 1 and m 2 are the masses of the objects, r is the distance between the centers of their masses, and G is the gravitational constant. The first test of Newton's law of gravitation between masses in the laboratory was the Cavendish experiment conducted by the British scientist Henry ...
F = total force acting on the center of mass m = mass of the body I 3 = the 3×3 identity matrix a cm = acceleration of the center of mass v cm = velocity of the center of mass τ = total torque acting about the center of mass I cm = moment of inertia about the center of mass ω = angular velocity of the body α = angular acceleration of the body
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
f. Physikal. Chemie 87. The Wohl equation (named after A. Wohl [5]) is formulated in terms of critical values, making it useful when real gas constants are not available, but it cannot be used for high densities, as for example the critical isotherm shows a drastic decrease of pressure when the volume is contracted beyond the critical volume.