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A thermodynamic cycle consists of linked sequences of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. [1]
The T-V diagram of the rubber band experiment. The decrease in the temperature of the rubber band in a spontaneous process at ambient temperature can be explained using the Helmholtz free energy = where dF is the change in free energy, dL is the change in length, τ is the tension, dT is the change in temperature and S is the entropy.
The Brayton cycle, also known as the Joule cycle, is a thermodynamic cycle that describes the operation of certain heat engines that have air or some other gas as their working fluid. It is characterized by isentropic compression and expansion, and isobaric heat addition and rejection, though practical engines have adiabatic rather than ...
An example of a cycle of idealized thermodynamic processes which make up the Stirling cycle. A quasi-static thermodynamic process can be visualized by graphically plotting the path of idealized changes to the system's state variables. In the example, a cycle consisting of four quasi-static processes is shown.
A schematic clockwise P-T-t path. Metamorphic minerals alter with the changing P-T condition with time without reaching complete phase equilibrium , making P-T-t path tracking possible. From 1910 Ma (i.e. 1910 million years ago) to 1840 Ma, the rock experienced an increase in P-T conditions and formed mineral garnet , which is attributed to ...
Equilibrium thermodynamic processes may involve fluxes but these must have ceased by the time a thermodynamic process or operation is complete bringing a system to its eventual thermodynamic state. Non-equilibrium thermodynamics allows its state variables to include non-zero fluxes, which describe transfers of mass or energy or entropy between ...
The cycle is reversible, meaning that if supplied with mechanical power, it can function as a heat pump for heating or cooling, and even for cryogenic cooling. The cycle is defined as a closed regenerative cycle with a gaseous working fluid. "Closed cycle" means the working fluid is permanently contained within the thermodynamic system.
The efficiency η of a thermogravitational cycle depends on the thermodynamic processes the working fluid goes through during each step of the cycle. Below some examples: If the heat exchanges at the bottom and top of the column with a hot source and cold source respectively, occur at constant pressure and temperature, the efficiency would be equal to the efficiency of a Carnot cycle: [1]