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Citric acid is a triprotic acid, with pK a values, extrapolated to zero ionic strength, of 3.128, 4.761, and 6.396 at 25 °C. [21] The pK a of the hydroxyl group has been found, by means of 13 C NMR spectroscopy, to be 14.4. [22] The speciation diagram shows that solutions of citric acid are buffer solutions between about pH 2 and pH 8. In ...
Acid–base extraction is a subclass of liquid–liquid extractions and involves the separation of chemical species from other acidic or basic compounds. [1] It is typically performed during the work-up step following a chemical synthesis to purify crude compounds [2] and results in the product being largely free of acidic or basic impurities.
Extraction in chemistry is a separation process consisting of the separation of a substance from a matrix. The distribution of a solute between two phases is an equilibrium condition described by partition theory.
Biological substances can experience leaching themselves, [2] as well as be used for leaching as part of the solvent substance to recover heavy metals. [6] Many plants experience leaching of phenolics, carbohydrates, and amino acids, and can experience as much as 30% mass loss from leaching, [5] just from sources of water such as rain, dew, mist, and fog. [2]
A buffer solution is a solution where the pH does not change significantly on dilution or if an acid or base is added at constant temperature. [1] Its pH changes very little when a small amount of strong acid or base is added to it. Buffer solutions are used as a means of keeping pH at a nearly constant value in a wide variety of chemical ...
Liquid–liquid extraction removes an impurity or recovers a desired product by dissolving the crude material in a solvent in which other components of the feed material are soluble. Crystallization separates a product from a liquid feed stream, often in extremely pure form, by cooling the feed stream or adding precipitants that lower the ...
% species formation calculated with the program HySS for a 10 millimolar solution of citric acid. pK a1 = 3.13, pK a2 = 4.76, pK a3 = 6.40. When the difference between successive pK values is less than about four there is overlap between the pH range of existence of the species in equilibrium. The smaller the difference, the more the overlap.
Similarly "spirit(s) of salt" actually meant hydrochloric acid. The concentrated, fuming, 35% acid is still sold under this name in the UK, for use as a drain-cleaning fluid. "Spirit of vinegar" is an antiquated term for glacial acetic acid "Spirit of vitriol" is an antiquated term for sulfuric acid