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In chemistry, absolute configuration refers to the spatial arrangement of atoms within a molecular entity (or group) that is chiral, and its resultant stereochemical description. [1] Absolute configuration is typically relevant in organic molecules where carbon is bonded to four different substituents .
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
A compass rose, showing absolute bearings in degrees. In nautical navigation the absolute bearing is the clockwise angle between north and an object observed from the vessel. If the north used as reference is the true geographical north then the bearing is a true bearing whereas if the reference used is magnetic north then the bearing is a ...
Pages for logged out editors learn more. Contributions; Talk; Absolute bearing
HSAB is widely used in chemistry for explaining the stability of compounds, reaction mechanisms and pathways. It assigns the terms 'hard' or 'soft', and 'acid' or 'base' to chemical species . 'Hard' applies to species which are small, have high charge states (the charge criterion applies mainly to acids, to a lesser extent to bases), and are ...
The α- and β-anomers of D-glucopyranose.. In organic chemistry, the anomeric effect or Edward-Lemieux effect (after J. T. Edward and Raymond Lemieux) is a stereoelectronic effect that describes the tendency of heteroatomic substituents adjacent to a heteroatom within a cyclohexane ring to prefer the axial orientation instead of the less-hindered equatorial orientation that would be expected ...
The chelate effect, below, is best explained in terms of thermodynamics. An equilibrium constant is related to the standard Gibbs free energy change for the reaction = R is the gas constant and T is the absolute temperature.
Absolute terms describe properties that are ideal in a Platonic sense, but that are not present in any concrete, real-world object. For example, while we say of many surfaces of physical things that they are flat, a rather reasonable interpretation of what we presumably observe makes it quite doubtful that these surfaces actually are flat.