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Generally, this process is similar to hydrogenation. The output is at three levels: heavy oil, middle oil, gasoline. The middle oil is hydrogenated in order to get more gasoline and the heavy oil is mixed with the coal again and the process restarts. In this way, heavy oil and middle oil fractions are also reused in this process.
Catalytic reforming requires a whole range of other processing units at the refinery (apart from the distillation tower, a naphtha hydrotreater, usually an isomerization unit to process light naphtha, an aromatics extraction unit, etc.) which puts it out of reach for smaller (micro-)refineries.
Although not practiced under the name, aromatization is a cornerstone of oil refining. One of the major reforming reactions is the dehydrogenation of paraffins and naphthenes into aromatics. The process, which is catalyzed by platinum supported by aluminium oxide, is exemplified in the conversion methylcyclohexane (a naphthene) into toluene (an ...
The STG+ process uses standard catalysts similar to those used in other gas to liquids technologies, specifically in methanol to gasoline processes. Methanol to gasoline processes favor molecular size- and shape-selective zeolite catalysts, [2] and the STG+ process also utilizes commercially available shape-selective catalysts, such as ZSM-5. [3]
The process was invented by Lewis Cass Karrick in the 1920s. The Karrick process is a low-temperature carbonization process, where coal is heated at 680 °F (360 °C) to 1,380 °F (750 °C) in the absence of air. These temperatures optimize the production of coal tars richer in lighter hydrocarbons than normal coal tar.
Since CO 2 in a non-polar compound has low surface tension and wets easily, it can be used to extract the typically hydrophobic aromatics from the plant material. This process is identical to one of the techniques for making decaffeinated coffee. In supercritical fluid extraction, high pressure carbon dioxide gas (up to 100 atm.) is used as a ...
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Another method entails methylation of phenol with methanol over a solid acid catalyst, often comprising magnesium oxide or alumina. Temperatures above 300 °C are typical. Anisole converts to cresols under these conditions. [5] [6] Another isomer of cresol is called Benzyl alcohol, or alpha-cresol (α-cresol).