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Example of a reduction–oxidation reaction between sodium and chlorine, with the OIL RIG mnemonic [1] Electron transfer (ET) occurs when an electron relocates from an atom, ion, or molecule, to another such chemical entity. ET describes the mechanism by which electrons are transferred in redox reactions. [2]
In outer sphere redox reactions no bonds are formed or broken; only an electron transfer (ET) takes place. A quite simple example is the Fe 2+ /Fe 3+ redox reaction, the self exchange reaction which is known to be always occurring in an aqueous solution containing the aquo complexes [Fe(H 2 O) 6] 2+ and [Fe(H 2 O)6] 3+.
First, the transfer of an electron from BPh − to P960 + is relatively slow compared to two other redox reactions in the reaction center. The faster reactions involve the transfer of an electron from BPh − (BPh − is oxidized to BPh) to the electron acceptor quinone (Q A ), and the transfer of an electron to P960 + (P960 + is reduced to ...
Inner sphere electron transfer (IS ET) or bonded electron transfer [1] is a redox chemical reaction that proceeds via a covalent linkage—a strong electronic interaction—between the oxidant and the reductant reactants. In inner sphere electron transfer, a ligand bridges the two metal redox centers during the electron transfer event. Inner ...
It is possible to introduce an artificial electron acceptor into the light reaction, such as a dye that changes color when it is reduced. These are known as Hill reagents. These dyes permitted the finding of electron transport chains during photosynthesis. Dichlorophenolindophenol (DCPIP), an example of these dyes, is widely used by experimenters.
A Proton-coupled electron transfer (PCET) is a chemical reaction that involves the transfer of electrons and protons from one atom to another. The term was originally coined for single proton, single electron processes that are concerted, [ 1 ] but the definition has relaxed to include many related processes.
An electron transport chain (ETC [1]) is a series of protein complexes and other molecules which transfer electrons from electron donors to electron acceptors via redox reactions (both reduction and oxidation occurring simultaneously) and couples this electron transfer with the transfer of protons (H + ions) across a membrane.
In most cases electron transfer can be assumed to be much faster than the chemical reactions. Unlike stoichiometric reactions where the steps between the starting materials and the rate limiting step dominate, in catalysis the observed reaction order is usually dominated by the steps between the catalytic resting state and the rate limiting step.