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For example, such a regulation might limit the concentration of NOx to 55 ppmv in a dry combustion exhaust gas corrected to 3 volume percent O 2. As another example, a regulation might limit the concentration of particulate matter to 0.1 grain per standard cubic foot (i.e., scf) of dry exhaust gas corrected to 12 volume percent CO 2.
Specific volume is a property of materials, defined as the number of cubic meters occupied by one kilogram of a particular substance. The standard unit is the meter cubed per kilogram (m 3 /kg or m 3 ·kg −1). Sometimes specific volume is expressed in terms of the number of cubic centimeters occupied by one gram of a substance.
The specific weight, also known as the unit weight (symbol γ, the Greek letter gamma), is a volume-specific quantity defined as the weight W divided by the volume V of a material: = / Equivalently, it may also be formulated as the product of density, ρ, and gravity acceleration, g: = Its unit of measurement in the International System of Units (SI) is newton per cubic metre (N/m 3), with ...
Mathematically, density is defined as mass divided by volume: [1] =, where ρ is the density, m is the mass, and V is the volume. In some cases (for instance, in the United States oil and gas industry), density is loosely defined as its weight per unit volume , [ 2 ] although this is scientifically inaccurate – this quantity is more ...
As an example, a measured NO x concentration of 45 ppmv in a dry gas having 5 volume % O 2 is: 45 × ( 20.9 - 3 ) ÷ ( 20.9 - 5 ) = 50.7 ppmv of NO x. when corrected to a dry gas having a specified reference O 2 content of 3 volume %. Note: The measured gas concentration C m must first be corrected to a dry basis before using the above equation.
This occurs because the molar mass of water vapor (18 g/mol) is less than the molar mass of dry air [note 2] (around 29 g/mol). For any ideal gas, at a given temperature and pressure, the number of molecules is constant for a particular volume (see Avogadro's Law ).
In chemistry, the mass concentration ρ i (or γ i) is defined as the mass of a constituent m i divided by the volume of the mixture V. [1]= For a pure chemical the mass concentration equals its density (mass divided by volume); thus the mass concentration of a component in a mixture can be called the density of a component in a mixture.
Relative density with respect to air can be obtained by =, where is the molar mass and the approximately equal sign is used because equality pertains only if 1 mol of the gas and 1 mol of air occupy the same volume at a given temperature and pressure, i.e., they are both ideal gases. Ideal behaviour is usually only seen at very low pressure.