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A salt with this anion is sometimes called an acid oxalate, monobasic oxalate, or hydrogen oxalate. The equilibrium constant (K a) for loss of the first proton is 5.37 × 10 −2 (pK a = 1.27). The loss of the second proton, which yields the oxalate ion, has an equilibrium constant of 5.25 × 10 −5 (pK a = 4.28).
Sodium oxalate, like citrates, can also be used to remove calcium ions (Ca 2+) from blood plasma. It also prevents blood from clotting . Note that by removing calcium ions from the blood , sodium oxalate can impair brain function, and deposit calcium oxalate in the kidneys .
Hydrogenoxalate or hydrogen oxalate (IUPAC name: 2-Hydroxy-2-oxoacetate) is an anion with chemical formula HC 2 O − 4 or HO−C(=O)−CO − 2, derived from oxalic acid by the loss of a single proton; or, alternatively, from the oxalate anion C 2 O 2− 4 by addition of a proton. The name is also used for any salt containing this anion.
Calcium oxalate is a combination of calcium ions and the conjugate base of oxalic acid, the oxalate anion. Its aqueous solutions are slightly basic because of the basicity of the oxalate ion. The basicity of calcium oxalate is weaker than that of sodium oxalate, due to its lower solubility in water.
It is a reducing agent [9] and its conjugate bases hydrogen oxalate (HC 2 O − 4) and oxalate (C 2 O 2− 4) are chelating agents for metal cations. It is used as a cleaning agent, especially for the removal of rust, because it forms a water-soluble ferric iron complex, the ferrioxalate ion.
Transition metal oxalate complexes are coordination complexes with oxalate (C 2 O 4 2−) ligands. Some are useful commercially, but the topic has attracted regular scholarly scrutiny. Oxalate (C 2 O 4 2-) is a kind of dicarboxylate ligand. [1] As a small, symmetrical dinegative ion, oxalate commonly forms five-membered MO 2 C 2 chelate rings.
Copper(II) oxalate are inorganic compounds with the chemical formula CuC 2 O 4 (H 2 O) x. The value of x can be 0, 0.44, and 1. The value of x can be 0, 0.44, and 1. Two of these species are found as secondary minerals (degradation of minerals), whewellite (monohydrate) and moolooite (0.44 hydrate). [ 3 ]
As can be read in the reference above, iron(III) sulfate, barium oxalate and potassium oxalate are combined in water and digested for several hours on a steam bath. Oxalate ions from barium oxalate will then replace the sulfate ions in solution, removing them as BaSO 4 which can then be filtered and the pure material can be crystallized.