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Birnessite (nominally MnO 2 ·nH 2 O), also known as δ-MnO 2, is a hydrous manganese dioxide mineral with a chemical formula of Na 0.7 Ca 0.3 Mn 7 O 14 ·2.8H 2 O. [5] It is the main manganese mineral species at the Earth's surface, and commonly occurs as fine-grained, poorly crystallized aggregates in soils, sediments, grain and rock coatings (e.g., desert varnish), and marine ferromanganese ...
Pyrolusite is a mineral consisting essentially of manganese dioxide (Mn O 2) and is important as an ore of manganese. [7] It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers.
Polymetallic nodules, also called manganese nodules, are mineral concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core. As nodules can be found in vast quantities, and contain valuable metals, deposits have been identified as a potential economic interest. [ 1 ]
Buserite is a hydrated layered manganese-oxide mineral with nominal chemical formula MnO 2 ·nH 2 O. It was named after Swiss chemist professor Wilhelm Buser (1917-1959), who first identified it in 1952 in deep-sea manganese nodules. Buser named it 10 Å manganate because the periodicity in the layer stacking direction was 10 Å.
The brown color of ceramic is sometimes the result of manganese compounds. [95] In the glass industry, manganese compounds are used for two effects. Manganese(III) reacts with iron(II) to reduce strong green color in glass by forming less-colored iron(III) and slightly pink manganese(II), compensating for the residual color of the iron(III). [ 45 ]
Two water molecules are complexed by the manganese cluster, which then undergoes a series of four electron removals (oxidations) to replenish the reaction center of photosystem II. At the end of this cycle, free oxygen ( O 2 ) is generated and the hydrogen of the water molecules has been converted to four protons released into the thylakoid ...
The advantage of combining powdered iron oxide and manganese oxide together is the lower melting point of the combined alloy compared to pure manganese oxide. [11] [12] In 1872, Lambert von Pantz produced ferromanganese in a blast furnace, with significantly higher manganese content than was previously possible (37% instead of the previous 12%).
Manganese deficiency in humans, which is rare, results in a number of medical problems. Many common vitamin and mineral supplement products fail to include manganese in their compositions. Relatively high dietary intake of other minerals such as iron, magnesium, and calcium may inhibit the proper intake of manganese.