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The hazards of ammonia solutions depend on the concentration: 'dilute' ammonia solutions are usually 5–10% by weight (< 5.62 mol/L); 'concentrated' solutions are usually prepared at >25% by weight. A 25% (by weight) solution has a density of 0.907 g/cm 3 , and a solution that has a lower density will be more concentrated.
Ammonia solutions decrease in density as the concentration of dissolved ammonia increases. At 15.6 °C (60.1 °F), the density of a saturated solution is 0.88 g/ml; it contains 35.6% ammonia by mass, 308 grams of ammonia per litre of solution, and has a molarity of approximately 18 mol/L.
This page provides supplementary chemical data on ammonia. Structure and properties. Molecular structure Point group: C 3v: Bond length: 101.2 pm (N–H) [1] Bond angle:
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged molecular ion with the chemical formula NH + 4 or [NH 4] +.It is formed by the addition of a proton (a hydrogen nucleus) to ammonia (NH 3).
Ammonium sulfate is made by treating ammonia with sulfuric acid: 2 NH 3 + H 2 SO 4 → (NH 4) 2 SO 4. A mixture of ammonia gas and water vapor is introduced into a reactor that contains a saturated solution of ammonium sulfate and about 2% to 4% of free sulfuric acid at 60 °C.
The B−N distance is 1.58(2) Å. The B−H and N−H distances are 1.15 and 0.96 Å, respectively. Its similarity to ethane is tenuous since ammonia borane is a solid and ethane is a gas: their melting points differing by 284 °C. This difference is consistent with the highly polar nature of ammonia borane.
The mixture easily converts to ammonia and hydrogen sulfide gases. This conversion illustrates the ease of the following equilibrium: [NH 4]SH ⇌ NH 3 + H 2 S. Ammonia and hydrogen sulfide each have a powerful and unpleasant smell. Solid ammonium hydrosulfide can be produced by reacting an equimolar mixture of ammonia and hydrogen sulfide ...
In chemistry, the amino radical, ·NH 2, also known as the aminyl or azanyl, is the neutral form of the amide ion (NH − 2).Aminyl radicals are highly reactive and consequently short-lived, like most radicals; however, they form an important part of nitrogen chemistry.