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Selenium forms two oxides: selenium dioxide (SeO 2) and selenium trioxide (SeO 3). Selenium dioxide is formed by the reaction of elemental selenium with oxygen: [5] + It is a polymeric solid that forms monomeric SeO 2 molecules in the gas phase. It dissolves in water to form selenous acid, H 2 SeO 3.
The element selenium exhibits several valence states. Selenate is the least reduced, followed by selenite, and elemental selenium; selenide is even more reduced than elemental selenium. [6] The valence state is an important factor to the toxicity of selenium. Selenate is the form required by organisms that need selenium as a micronutrient.
Selenium hexafluoride is the inorganic compound with the formula SeF 6. It is a very toxic colourless gas described as having a "repulsive" odor. [ 5 ] It is not widely encountered and has no commercial applications.
Selenium oxydichloride is the inorganic compound with the formula SeOCl 2. It is a colorless liquid. With a high dielectric constant (55) and high specific conductance, it is an attractive solvent. Structurally, it is a close chemical relative of thionyl chloride SOCl 2, being a pyramidal molecule.
Selenium is found in metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells.
Selenite refers to the anion with the chemical formula Se O 2− 3. It is the oxyanion of selenium. It is the selenium analog of the sulfite ion, SO 2− 3. Thus selenite is pyramidal and selenium is assigned oxidation state +4. Selenite also refers to compounds that contains this ion, for example sodium selenite Na 2 SeO 3 which is a common ...
Selenium tetrachloride is the inorganic compound composed with the formula SeCl 4. This compound exists as yellow to white volatile solid. This compound exists as yellow to white volatile solid. It is one of two commonly available selenium chlorides , the other example being selenium monochloride , Se 2 Cl 2 .
Lithium selenide is an inorganic compound that formed by selenium and lithium. It is a selenide with a chemical formula Li 2 Se. Lithium selenide has the same crystal form as other selenides, which is cubic, belonging to the anti-fluorite structure , the space group is F m 3 ¯ m {\displaystyle Fm{\bar {3}}m} , each unit cell has 4 units.