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Gas stoichiometry is the quantitative relationship (ratio) between reactants and products in a chemical reaction with reactions that produce gases. Gas stoichiometry applies when the gases produced are assumed to be ideal, and the temperature, pressure, and volume of the gases are all known. The ideal gas law is used for these calculations.
Within chemistry, a Job plot, otherwise known as the method of continuous variation or Job's method, is a method used in analytical chemistry to determine the stoichiometry of a binding event. The method is named after Paul Job and is also used in instrumental analysis and advanced chemical equilibrium texts and research articles.
The law of definite proportion was given by Joseph Proust in 1797. [2]I shall conclude by deducing from these experiments the principle I have established at the commencement of this memoir, viz. that iron like many other metals is subject to the law of nature which presides at every true combination, that is to say, that it unites with two constant proportions of oxygen.
The amine value is useful in helping determine the correct stoichiometry of a two component amine cure epoxy resin system. [6] [7] [8]It is the number of Nitrogens x 56.1 (Mwt of KOH) x 1000 (convert to milligrams) divided by molecular mass of the amine functional compound.
The composition of a non-stoichiometric compound usually varies in a continuous manner over a narrow range. Thus, the formula for wüstite is written as Fe 1−x O, where x is a small number (0.05 in the previous example) representing the deviation from the "ideal" formula. [3]
In physical chemistry and chemical engineering, extent of reaction is a quantity that measures the extent to which the reaction has proceeded. Often, it refers specifically to the value of the extent of reaction when equilibrium has been reached.
For his 1934 paper, Alfred Redfield analyzed nitrate and phosphate data for the Atlantic, Indian, Pacific oceans and Barents Sea. [1] As a Harvard physiologist, Redfield participated in several voyages on board the research vessel Atlantis, analyzing data for C, N, and P content in marine plankton, and referenced data collected by other researchers as early as 1898.
Trimethylborane spontaneously ignites in air if the concentration is high enough. It burns with a green flame producing soot. [11] Slower oxidation with oxygen in a solvent or in the gas phase can produce dimethyltrioxadiboralane, which contains a ring of two boron and three oxygen atoms.