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Change in volume with increasing ethanol fraction. The molar volume of a substance i is defined as its molar mass divided by its density ρ i 0: , = For an ideal mixture containing N components, the molar volume of the mixture is the weighted sum of the molar volumes of its individual components.
The molar volume of the reference fluid methane, which is used to calculate the mass density in the viscosity formulas above, is calculated at a reduced temperature that is proportional to the reduced temperature of the mixture.
[1] [9] According to this, the mixing temperature is the weighted arithmetic mean of the temperatures of the two initial components. Richmann's rule of mixing can also be applied in reverse, for example, to the question of the ratio in which quantities of water of given temperatures must be mixed to obtain water of a desired temperature.
The inset in Figure A shows the mixture states, which are a combination of the saturated liquid and vapor states that correspond to each end of the horizontal mixture line (that is, the points of intersection between the mixture line and its isotherm). However, these mixture states are not part of the surface generated by the van der Waals ...
The volume of such a mixture is slightly less than the sum of the volumes of the components. Thus, by the above definition, the term "40% alcohol by volume" refers to a mixture of 40 volume units of ethanol with enough water to make a final volume of 100 units, rather than a mixture of 40 units of ethanol with 60 units of water.
The usage of the pre-SI units has only historic reasons and originates directly from Antoine's original publication. It is however easy to convert the parameters to different pressure and temperature units. For switching from degrees Celsius to kelvin it is sufficient to subtract 273.15 from the C parameter.
In this case, the unit is the centimeter cubed per gram (cm 3 /g or cm 3 ·g −1). To convert m 3 /kg to cm 3 /g, multiply by 1000; conversely, multiply by 0.001. Specific volume is inversely proportional to density. If the density of a substance doubles, its specific volume, as expressed in the same base units, is cut in half.
Also known as volumetric blending. This must be done at constant temperature for best accuracy, though it is possible to compensate for temperature changes in proportion to the accuracy of the temperature measured before and after each gas is added to the mixture. Partial pressure blending is commonly used for breathing gases for diving.