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Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula C H 2 Cl 2. This colorless, volatile liquid with a chloroform-like, sweet odor is widely used as a solvent. Although it is not miscible with water, it is slightly polar, and miscible with many organic solvents. [12]
A polar aprotic solvent is a solvent that lacks an acidic proton and is polar. Such solvents lack hydroxyl and amine groups. In contrast to protic solvents, these solvents do not serve as proton donors in hydrogen bonding, although they can be proton acceptors. Many solvents, including chlorocarbons and hydrocarbons, are classifiable as aprotic ...
Solvent Density (g cm-3) Boiling point (°C) K b (°C⋅kg/mol) ... Dichloromethane: 1.33 39.8 [22] n-Propanol: 97.2 [23] Pyridine: 115.3 [24] Dimethylacetamide: 166. ...
Polar aprotic solvents, such as acetone or dichloromethane, tend to have large dipole moments (separation of partial positive and partial negative charges within the same molecule) and solvate positively charged species via their negative dipole. [11]
log 10 of Dichloromethane vapor pressure. Uses formula: log e P m m H g = {\displaystyle \scriptstyle \log _{e}P_{mmHg}=} log e ( 760 101.325 ) − 10.08632 log e ( T + 273.15 ) − 6030.610 T + 273.15 + 80.87786 + 9.812512 × 10 − 6 ( T + 273.15 ) 2 {\displaystyle \scriptstyle \log _{e}({\frac {760}{101.325}})-10.08632\log _{e ...
This arises from the fact that polar solvents stabilize the formation of the carbocation intermediate to a greater extent than the non-polar-solvent conditions. This is apparent in the ΔE a, ΔΔG ‡ activation. On the right is an S N 2 reaction coordinate diagram. Note the decreased ΔG ‡ activation for the non-polar-solvent reaction ...
Dichloromethane, a common solvent in organic chemistry; Deep chlorophyll maximum, subsurface maximum in the concentration of chlorophyll; Dynamic causal modelling, a method for the interpretation of functional neuroimaging data; Docking Cargo Module, A Russian module of the International Space Station; Dilated cardiomyopathy, a heart condition
In general terms, any solvent that contains a labile H + is called a protic solvent. The molecules of such solvents readily donate protons (H +) to solutes, often via hydrogen bonding. Water is the most common protic solvent. Conversely, polar aprotic solvents cannot donate protons but still have the ability to dissolve many salts. [1] [2]