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For groundwater "potentiometric surface" is a synonym of "piezometric surface" which is an imaginary surface that defines the level to which water in a confined aquifer would rise were it completely pierced with wells. [1] If the potentiometric surface lies above the ground surface, a flowing artesian well results.
In fact, since the potentiometric measurement is a non-destructive measurement, assuming that the electrode is in equilibrium with the solution, we are measuring the solution's potential. Potentiometry usually uses indicator electrodes made selectively sensitive to the ion of interest, such as fluoride in fluoride selective electrodes , so that ...
Typically this equation is used to find the average T and S values near a pumping well, from drawdown data collected during an aquifer test. This is a simple form of inverse modeling, since the result ( s ) is measured in the well, r , t , and Q are observed, and values of T and S which best reproduce the measured data are put into the equation ...
For general purposes, buffers at pH 4.00 and pH 10.00 are suitable. The pH meter has one calibration control to set the meter reading equal to the value of the first standard buffer and a second control to adjust the meter reading to the value of the second buffer. A third control allows the temperature to be set.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
To make a potentiometric determination of an analyte in a solution, the potential of the cell is measured. This measurement must be corrected for the reference and junction potentials. It can also be used in standardisation methods. The concentration of the analyte can then be calculated from the Nernst Equation. Many varieties of this basic ...
A potentiometric sensor is a type of chemical sensor that may be used to determine the analytical concentration of some components of the analyte gas or solution.
To use potentiometric (e.m.f.) measurements in monitoring the + concentration in place of readings, one can trivially set [+] = and apply the same equations as above, where is the offset correction /, and is a slope correction / (1/59.2 pH units/mV at 25°C), such that replaces .