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The pictogram for harmful substances of the Globally Harmonized System of Classification and Labelling of Chemicals.. The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) is an internationally agreed-upon standard managed by the United Nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around ...
P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. P282: Wear cold insulating gloves and either face shield or eye protection.
Statements which correspond to related hazards are grouped together by code number, so the numbering is not consecutive. The code is used for reference purposes, for example to help with translations, but it is the actual phrase which should appear on labels and safety data sheets. [4]
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible. S63 In case of accident by inhalation: remove casualty to fresh air and keep at rest. S64 If swallowed, rinse mouth with water (only if the person is conscious). Combinations of S phrases. S1/2
Example: R: 34-37 Causes burns, irritating to the respiratory system. Slashes indicate fixed combinations of single phrases. Example: R: 36/37/38 Irritating to eyes, respiratory system and skin. More detailed hazard and safety information can be found in the material safety data sheets (MSDS) of a compound.
Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. P282: Wear cold insulating gloves and either face shield or eye protection. P283
ANSI Z535 standards integrate with international ISO 3864 standards, ensuring the widest compliance, globally, with export/import laws. ANSI Z535 standardized HazCom may appear on workplace walls, industrial machines, at industrial access points, on electrical controls, inside product user guides, and on export documentation.
This system was brought into alignment with GHS in 2015, with a gradual phase in of GHS symbols and label designs through 15 December 2025. [25] The WHMIS system does deviate from GHS by retaining the former WHMIS symbol for Class 3, Division 3, biohazardous infectious materials , as GHS lacks a biological hazard symbol.