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Dihydroxyacetone phosphate, one of the two products of breakdown of fructose 1,6-bisphosphate, is a precursor to methylglyoxal. This conversion is the basis of a potential biotechnological route to the commodity chemical 1,2-propanediol. Three-carbon deoxysugars are also precursor to the 1,2-diol. [7]
Propanediol may refer to any of four isomeric organic chemical compounds: Non-geminal diols (glycols) 1,2-Propanediol, a.k.a. propylene glycol, a vicinal diol;
RC(O)CH 2 CH 2 OH + H 2 → RCH(OH)CH 2 CH 2 OH. 2,2-Disubstituted propane-1,3-diols are prepared in this way. Examples include 2-methyl-2-propyl-1,3-propanediol and neopentyl glycol. 1,3-Diols can be prepared by hydration of α,β-unsaturated ketones and aldehydes. The resulting keto-alcohol is hydrogenated.
The molecular formula C 3 H 8 O 2 may refer to: Dimethoxymethane; 2-Methoxyethanol; Propanediol. 1,2-Propanediol (propylene glycol), a vicinal diol; 1,3-Propanediol (trimethylene glycol) 1,1-Propanediol (geminal diol) 2,2-Propanediol (geminal diol)
1,3-Propanediol is mainly produced by the hydration of acrolein. An alternative route involves the hydroformylation of ethylene oxide to form 3-hydroxypropionaldehyde. The aldehyde is subsequently hydrogenated to give 1,3-propanediol. Biotechnological routes are also known. [2] Two other routes involve bioprocessing by certain micro-organisms:
CH 3 CHCH 2 O + CO 2 → CH 3 C 2 H 3 O 2 CO. The corresponding reaction of 1,2-propanediol with phosgene is complex, yielding not only propylene carbonate but also oligomeric products. Propylene carbonate can also be synthesized from urea and propylene glycol over zinc acetate. [6]
A Mass General Brigham emergency care doctor shares step-by-step guidance on how to administer the Heimlich maneuver to adults, children and yourself in a choking event.
In enzymology, a lactaldehyde reductase (NADPH) (EC 1.1.1.55) is an enzyme that catalyzes the chemical reaction. propane-1,2-diol + NADP + L-lactaldehyde + NADPH + H +. Thus, the two substrates of this enzyme are 1,2-propanediol and NADP +, whereas its 3 products are L-lactaldehyde, NADPH, and H +.