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In practice the molar ionic conductivities are calculated from the measured ion transport numbers and the total molar conductivity. For the cation + = + +, and similarly for the anion. In solutions, where ionic complexation or associaltion are important, two different transport/transference numbers can be defined.
When charged particles move in electric and magnetic fields the following two laws apply: Lorentz force law: = (+),; Newton's second law of motion: = =; where F is the force applied to the ion, m is the mass of the particle, a is the acceleration, Q is the electric charge, E is the electric field, and v × B is the cross product of the ion's velocity and the magnetic flux density.
The Nernst–Planck equation is a conservation of mass equation used to describe the motion of a charged chemical species in a fluid medium. It extends Fick's law of diffusion for the case where the diffusing particles are also moved with respect to the fluid by electrostatic forces.
In particle physics, the electron mass (symbol: m e) is the mass of a stationary electron, also known as the invariant mass of the electron. It is one of the fundamental constants of physics . It has a value of about 9.109 × 10 −31 kilograms or about 5.486 × 10 −4 daltons , which has an energy-equivalent of about 8.187 × 10 −14 joules ...
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.
In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
where M is the molar mass of the substance (usually given in SI units of grams per mole) and v is the valency of the ions. For Faraday's first law, M, F, v are constants; thus, the larger the value of Q , the larger m will be.