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Liquidus and solidus are mostly used for impure substances (mixtures) such as glasses, metal alloys, ceramics, rocks, and minerals. Lines of liquidus and solidus appear in the phase diagrams of binary solid solutions , [ 2 ] as well as in eutectic systems away from the invariant point.
The solidus is the temperature below which the substance is stable in the solid state. The liquidus is the temperature above which the substance is stable in a liquid state. There may be a gap between the solidus and liquidus; within the gap, the substance consists of a mixture of crystals and liquid (like a "slurry"). [2]
In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram.It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
The fourth condition (straight solidus/liquidus segments) may be relaxed when numerical techniques are used, such as those used in CALPHAD software packages, though these calculations rely on calculated equilibrium phase diagrams. Calculated diagrams may include odd artifacts (i.e. retrograde solubility) that influence Scheil calculations.
A phase diagram for a fictitious binary chemical mixture (with the two components denoted by A and B) used to depict the eutectic composition, temperature, and point. ( L denotes the liquid state.) A eutectic system or eutectic mixture ( / j uː ˈ t ɛ k t ɪ k / yoo- TEK -tik ) [ 1 ] is a type of a homogeneous mixture that has a melting point ...
[4] [5] [6] The CALPHAD approach is based on the fact that a phase diagram is a manifestation of the equilibrium thermodynamic properties of the system, which are the sum of the properties of the individual phases. [7] It is thus possible to calculate a phase diagram by first assessing the thermodynamic properties of all the phases in a system.
This diagram shows the nomenclature for the different phase transitions. In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another.
Alloys have a melting point range. It solidifies as shown in the figure above. First, the molten alloy reaches to liquidus temperature and then freezing range starts. At solidus temperature, the molten alloy becomes solid.