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Micellar originates from France, with its usage in skincare dating back to 1913. [5] Its popularity boomed internationally when French pharmaceutical company Bioderma released their product Sensibio H2O micellar water in 1991, which is said to be sold every two seconds worldwide today. [6]
A micellar cubic phase is a lyotropic liquid crystal phase formed when the concentration of micelles dispersed in a solvent (usually water) is sufficiently high that they are forced to pack into a structure having a long-ranged positional (translational) order. For example, spherical micelles a cubic packing of a body-centered cubic lattice.
The driving mechanism for micellization is the transfer of hydrocarbon chains from water into the oil-like interior. This entropic effect is called the hydrophobic effect. Compared to the increase of entropy of the surrounding water molecules, this hydrophobic interaction is relatively small. The water molecules are highly ordered around the ...
An amphiphilic behavior can be observed for water and an organic solvent or between two organic solvents. Note 2: Polymeric micelles have a much lower critical micellar concentration (CMC) than soap (0.0001 to 0.001 mol/L) or surfactant micelles, but are nevertheless at equilibrium with isolated macromolecules called unimers.
Light scattering should not be a concern due to the small size, a few nanometers, of the micelle. [1] The effect of organic additives on micellar properties is another important consideration. A small amount of organic solvent is often added to the mobile phase to help improve efficiency and to improve separations of compounds.
While some carbonated water is natural, created as volcanic gases infuse the water in natural springs with bubbles and minerals, most sparkling water is made by forcing carbon dioxide, or CO2 ...
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