Ad
related to: cis-2-butene
Search results
Results From The WOW.Com Content Network
But-2-ene is an acyclic alkene with four carbon atoms. It is the simplest alkene exhibiting cis/trans-isomerism (also known as (E/Z)-isomerism); that is, it exists as two geometric isomers cis-but-2-ene ((Z)-but-2-ene) and trans-but-2-ene ((E)-but-2-ene). It is a petrochemical, produced by the catalytic cracking of crude oil or the dimerization ...
cis-but-2-ene trans-but-2-ene. Cis–trans isomerism, also known as geometric isomerism, describes certain arrangements of atoms within molecules.The prefixes "cis" and "trans" are from Latin: "this side of" and "the other side of", respectively. [1]
For example, of the isomers of butene, the two methyl groups of (Z)-but-2-ene (a.k.a. cis-2-butene) appear on the same side of the double bond, and in (E)-but-2-ene (a.k.a. trans-2-butene) the methyl groups appear on opposite sides. These two isomers of butene have distinct properties.
For example, the relative rates of epoxidation increase upon methyl substitution of the alkene (the methyl groups increase the electron density of the double bond by hyperconjugation): ethylene (1, no methyl groups), propene (24, one methyl group), cis-2-butene (500, two methyl groups), 2-methyl-2-butene (6500, three methyl groups), 2,3 ...
For example, 2-butene exists in two isomeric forms: cis-2-butene and trans-2-butene. [2] The sub-categories of isomerases containing racemases, epimerases and cis-trans isomers are examples of enzymes catalyzing the interconversion of stereoisomers.
Trans-alkenes are about 1 kcal/mol more stable than cis-alkenes. An example of this effect is cis- vs trans-2-butene. The difference is attributed to unfavorable non-bonded interactions in the cis isomer. Terminal alkenes isomerize to internal alkenes in the presence of metal catalysts.
[5] [6] Examples of the latter are the enantiomers, whose molecules are mirror images of each other, and the cis and trans versions of 2-butene. Among the structural isomers, one can distinguish several classes including skeletal isomers, positional isomers (or regioisomers), functional isomers, tautomers, [7] and structural isotopomers. [8]
Brattain's examination of isomers proved doubly important to the war effort. In addition to the C4 hydrocarbon isomers isobutane and n-butane (important in aviation fuels) Brattain was able to identify a set of four butenes, 1-butene, cis-2-butene, trans-2-butene, and isobutene.