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A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs . The stable balance of attractive and repulsive forces between atoms, when they share electrons , is known as covalent bonding. [ 1 ]
Bent's rule predicts that, in order to stabilize the unshared, closely held nonbonding electrons, lone pair orbitals should take on high s character. On the other hand, an unoccupied (empty) nonbonding orbital can be thought of as the limiting case of an electronegative substituent, with electron density completely polarized towards the ligand ...
As noted above, covalent and ionic bonds form a continuum between shared and transferred electrons; covalent and weak bonds form a continuum between shared and unshared electrons. In addition, molecules can be polar, or have polar groups, and the resulting regions of positive and negative charge can interact to produce electrostatic bonding ...
In (a) the two nuclei are surrounded by a cloud of two electrons in the bonding orbital that holds the molecule together. (b) shows hydrogen's antibonding orbital, which is higher in energy and is normally not occupied by any electrons. A chemical bond is the association of atoms or ions to form molecules, crystals, and other
Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. [1] An atom's electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus.
Bond order is the number of chemical bonds between a pair of atoms. The bond order of a molecule can be calculated by subtracting the number of electrons in anti-bonding orbitals from the number of bonding orbitals, and the resulting number is then divided by two. A molecule is expected to be stable if it has bond order larger than zero.
Such an atom has the following electron configuration: s 2 p 5; this requires only one additional valence electron to form a closed shell. To form an ionic bond, a halogen atom can remove an electron from another atom in order to form an anion (e.g., F −, Cl −, etc.). To form a covalent bond, one electron from the halogen and one electron ...
In both cases a bond is created by the formation of an electron pair. Because electrons are fermions, the Pauli exclusion principle forbids these particles from having all the same quantum numbers. Therefore, for two electrons to occupy the same orbital, and thereby have the same orbital quantum number, they must have different spin quantum ...