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This website is also cited in the CRC Handbook as source of Section 1, subsection Electron Configuration of Neutral Atoms in the Ground State. 91 Pa : [Rn] 5f 2 (3 H 4) 6d 7s 2; 92 U : [Rn] 5f 3 (4 I o 9/2) 6d 7s 2; 93 Np : [Rn] 5f 4 (5 I 4) 6d 7s 2; 103 Lr : [Rn] 5f 14 7s 2 7p 1 question-marked; 104 Rf : [Rn] 5f 14 6d 2 7s 2 question-marked
For example, the electron configuration of the titanium ground state can be written as either [Ar] 4s 2 3d 2 or [Ar] 3d 2 4s 2. The first notation follows the order based on the Madelung rule for the configurations of neutral atoms; 4s is filled before 3d in the sequence Ar, K, Ca, Sc, Ti.
Configurations of elements 109 and above are not available. Predictions from reliable sources have been used for these elements. Grayed out electron numbers indicate subshells filled to their maximum. Bracketed noble gas symbols on the left represent inner configurations that are the same in each period. Written out, these are: He, 2, helium : 1s 2
The lightest atom that requires the second rule to determine the ground state term is titanium (Ti, Z = 22) with electron configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 2 4s 2. In this case the open shell is 3d 2 and the allowed terms include three singlets ( 1 S, 1 D, and 1 G) and two triplets ( 3 P and 3 F).
Neutral atoms of the chemical elements have the same term symbol for each column in the s-block and p-block elements, but differ in d-block and f-block elements where the ground-state electron configuration changes within a column, where exceptions to Hund's rules occur. Ground state term symbols for the chemical elements are given below.
Relativistic stabilization of the 8p subshell should result in a ground-state 8s 2 8p 1 valence electron configuration for element 121, in contrast to the ds 2 configurations of lanthanum and actinium; [15] nevertheless, this anomalous configuration does not appear to affect its calculated chemistry, which remains similar to that of actinium. [82]
The group is also called the titanium group or titanium family after its lightest member. As is typical for early transition metals, zirconium and hafnium have only the group oxidation state of +4 as a major one, and are quite electropositive and have a less rich coordination chemistry.
The more interesting case is when the material's electron spontaneously break above-mentioned symmetry. For ferromagnetism in the ground state, there is a common spin quantization axis and a global excess of electrons of a given spin quantum number, there are more electrons pointing in one direction than in the other, giving a macroscopic ...