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Indium Corporation is a materials refiner, smelter, manufacturer, and supplier to the global electronics, semiconductor, thin-film, and thermal management markets.Products include solders and fluxes; brazes; thermal interface materials; sputtering targets; indium, gallium, germanium, and tin metals and inorganic compounds; and NanoFoil.
The first organogermanium compound, tetraethylgermane, synthesized by Winkler in 1887, [3] by the reaction of germanium tetrachloride with diethylzinc. More commonly, these Ge(IV) compounds are prepared by alkylation of germanium halides by organolithium and Grignard reagents, including surfaces terminated with Ge-Cl bonds. [4]
Two oxides of germanium are known: germanium dioxide (GeO 2, germania) and germanium monoxide, (GeO). [4] The dioxide, GeO 2 can be obtained by roasting germanium disulfide (GeS 2) or by allowing elemental germanium to slowly oxidze in air, [5] and is a white powder that is only slightly soluble in water but reacts with alkalis to form germanates. [4]
China on Tuesday banned exports to the United States of the critical minerals gallium, germanium and antimony that have widespread military applications, escalating trade tensions the day after ...
Sigma Chemical Company of St. Louis and Aldrich Chemical Company of Milwaukee were both American specialty chemical companies when they merged in August 1975. The company grew throughout the 1980s and 1990s, with significant expansion in facilities, acquisitions and diversification into new market sectors.
Organic germanium hydrides such as isobutylgermane ((CH 3) 2 CHCH 2 GeH 3) were found to be less hazardous and may be used as a liquid substitute for toxic germane gas in semiconductor applications. Many germanium reactive intermediates are known: germyl free radicals, germylenes (similar to carbenes), and germynes (similar to carbynes).
A number of elements are recovered in flue gas and flue dust in zinc smelters. These include the metal cadmium and the semi-metals gallium and germanium. In 1970, for every ton of zinc produced at a US smelter, there were also recovered 4.2 kilograms of cadmium, 53 grams of germanium, 18 grams of indium, and 2.9 grams of thallium. [13]
The first example of organogermanes used in transition-metal-catalyzed cross-coupling reaction was reported in 2004. [1] However, due to the toxicity, low reactivity (compared with other Ar–[M] nucleophiles) and poor stability of ArGeCl 3, this reaction was demonstrated not to be synthetically applicable.