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The only hydrates with stable melting points are NaOH·H 2 O (65.10 °C) and NaOH·3.5H 2 O (15.38 °C). The other hydrates, except the metastable ones NaOH·3H 2 O and NaOH·4H 2 O (β) can be crystallized from solutions of the proper composition, as listed above. However, solutions of NaOH can be easily supercooled by many degrees, which ...
4 NaClO + Na 2 S 2 O 3 + 2 NaOH → 4 NaCl + 2 Na 2 SO 4 + H 2 O. Similarly, sodium thiosulfate reacts with bromine, removing the free bromine from the solution. Solutions of sodium thiosulfate are commonly used as a precaution in chemistry laboratories when working with bromine and for the safe disposal of bromine, iodine, or other strong ...
The elementary reaction responsible for water quantification in the Karl Fischer titration is oxidation of sulfur dioxide (SO 2) with iodine: . H 2 O + SO 2 + I 2 → SO 3 + 2 HI. This elementary reaction consumes exactly one molar equivalent of water vs. iodine.
Sodium sulfite (sodium sulphite) is the inorganic compound with the chemical formula Na 2 SO 3.A white, water-soluble solid, it is used commercially as an antioxidant and preservative.
The molecule SO 3 is trigonal planar.As predicted by VSEPR theory, its structure belongs to the D 3h point group.The sulfur atom has an oxidation state of +6 and may be assigned a formal charge value as low as 0 (if all three sulfur-oxygen bonds are assumed to be double bonds) or as high as +2 (if the Octet Rule is assumed). [7]
SO 2 + NaOH → NaHSO 3 SO 2 + NaHCO 3 → NaHSO 3 + CO 2. Attempts to crystallize the product yield sodium metabisulfite (also called sodium disulfite), Na 2 S 2 O 5. [6] Upon dissolution of the metabisulfite in water, bisulfite is regenerated: Na 2 S 2 O 5 + H 2 O → 2 Na + + 2 HSO 3 −. Sodium bisulfite is formed during the Wellman-Lord ...
In chemistry, molecular autoionization (or self-ionization) is a chemical reaction between molecules of the same substance to produce ions.If a pure liquid partially dissociates into ions, it is said to be self-ionizing.
In organic chemistry, the Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol (−OH) is oxidized to an aldehyde (−CH=O) or ketone (>C=O) using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine.