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The grain boundary diffusion coefficient is the diffusion coefficient of a diffusant along a grain boundary in a polycrystalline solid. [1] It is a physical constant denoted , and it is important in understanding how grain boundaries affect atomic diffusivity. Grain boundary diffusion is a commonly observed route for solute migration in ...
In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional defects in the crystal structure , and tend to decrease the electrical and thermal conductivity of the material.
Grain boundary engineering involves manipulating the grain boundary structure and energy to enhance mechanical properties. By controlling the interfacial energy, it is possible to engineer materials with desirable grain boundary characteristics, such as increased interfacial area, higher grain boundary density, or specific grain boundary types ...
Grain growth has long been studied primarily by the examination of sectioned, polished and etched samples under the optical microscope.Although such methods enabled the collection of a great deal of empirical evidence, particularly with regard to factors such as temperature or composition, the lack of crystallographic information limited the development of an understanding of the fundamental ...
Nonmetallic impurities often aggregate at grain boundaries and have the ability to impact the strength of materials by changing the grain boundary energy. Rupert et al. [26] conducted first-principles simulations to study the impact of the addition of common nonmetallic impurities on Σ5 (310) grain boundary energy in Cu. They claimed that the ...
These precipitates can also pin the grain boundary at higher temperatures, essentially acting as "friction". Another useful effect can be to impede grain-boundary sliding under diffusional creep conditions with very fine precipitates and if the precipitates are homogeneously dispersed in the matrix, then these same precipitates in the grains ...
Hume-Rothery rules, named after William Hume-Rothery, are a set of basic rules that describe the conditions under which an element could dissolve in a metal, forming a solid solution. There are two sets of rules; one refers to substitutional solid solutions, and the other refers to interstitial solid solutions.
Zener pinning is the influence of a dispersion of fine particles on the movement of low- and high-angle grain boundaries through a polycrystalline material. Small particles act to prevent the motion of such boundaries by exerting a pinning pressure which counteracts the driving force pushing the boundaries.