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Organotin chemistry is the scientific study of the synthesis and properties of organotin compounds or stannanes, which are organometallic compounds containing tin–carbon bonds. The first organotin compound was diethyltin diiodide ( (CH 3 CH 2 ) 2 SnI 2 ), discovered by Edward Frankland in 1849. [ 1 ]
As with other elements, the simplest compounds of copper are binary compounds, i.e. those containing only two elements, the principal examples being oxides, sulfides, and halides. Both cuprous and cupric oxides are known. Among the numerous copper sulfides, important examples include copper(I) sulfide and copper(II) sulfide. [citation needed]
Tin(II) hydroxide – Sn(OH) 2; Tin(II) iodide – SnI 2; Tin(II) oxide – SnO; Tin(II) sulfate – SnSO 4; Tin(II) sulfide – SnS; Tin(IV) bromide – SnBr 4; Tin(IV) chloride – SnCl 4; Tin(IV) fluoride – SnF 4; Tin(IV) iodide – SnI 4; Tin(IV) oxide – SnO 2; Tin(IV) sulfide – SnS 2; Tin(IV) cyanide – Sn(CN) 4; Tin selenide ...
When not cooled below −5 °C (23 °F), copper hydride decomposes, to produce hydrogen gas and a mixture containing elemental copper: 2 CuH → xCu•(2-x)CuH + ½x H 2 (0 < x < 2) Solid copper hydride is the irreversible autopolymerisation product of the molecular form, and the molecular form cannot be isolated in concentration.
Stannane / ˈ s t æ n eɪ n / or tin hydride is an inorganic compound with the chemical formula Sn H 4. It is a colourless gas and the tin analogue of methane . Stannane can be prepared by the reaction of SnCl 4 and Li[AlH 4 ] .
A solution of tin(II) chloride containing a little hydrochloric acid is used for the tin-plating of steel, in order to make tin cans. An electric potential is applied, and tin metal is formed at the cathode via electrolysis. Tin(II) chloride is used as a mordant in textile dyeing because it gives brighter colours with some dyes e.g. cochineal ...
Copper is a chemical element with the symbol Cu (from Latin: cuprum) and the atomic number of 29. It is easily recognisable, due to its distinct red-orange color . Copper also has a range of different organic and inorganic salts , having varying oxidation states ranging from (0,I) to (III).
Classically, the structures of metal hydrides was addressed by neutron diffraction since hydrogen strongly scatters neutrons. [13] Metal complexes containing terminal hydrides are common. In bi- and polynuclear compounds, hydrides usually are bridging ligands. Of these bridging hydrides many are oligomeric, such as Stryker's reagent. [14] [