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Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
The downward arrow "electron affinity" shows the negative quantity –EA F, since EA F is usually defined as positive. For ionic compounds, the standard enthalpy of formation is equivalent to the sum of several terms included in the Born–Haber cycle. For example, the formation of lithium fluoride,
The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: . Temperature 298.15 K (25.00 °C; 77.00 °F); ...
Aluminium's electropositive behavior, high affinity for oxygen, and highly negative standard electrode potential are all more similar to those of scandium, yttrium, lanthanum, and actinium, which have ds 2 configurations of three valence electrons outside a noble gas core: aluminium is the most electropositive metal in its group. [1]
where I is the ionization potential and A the electron affinity. This expression implies that the chemical hardness is proportional to the band gap of a chemical system, when a gap exists. The first derivative of the energy with respect to the number of electrons is equal to the chemical potential , μ , of the system,
The energy released when an electron is added to a neutral gaseous atom to form an anion is known as electron affinity. [14] Trend-wise, as one progresses from left to right across a period , the electron affinity will increase as the nuclear charge increases and the atomic size decreases resulting in a more potent force of attraction of the ...
In chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. [1] Chemical affinity can also refer to the tendency of an atom or compound to combine by chemical reaction with atoms or compounds of unlike composition.