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Acetonitrile, often abbreviated MeCN (methyl cyanide), is the chemical compound with the formula CH 3 CN and structure H 3 C−C≡N. This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not classed as organic). It is produced mainly as a byproduct of acrylonitrile manufacture.
[Cu(MeCN) 4] +, often encountered as its PF 6 − salt, is a common transition metal nitrile complex. Transition metal nitrile complexes are coordination compounds containing nitrile ligands. Because nitriles are weakly basic, the nitrile ligands in these complexes are often labile .
The cation was first reported in 1923 with a nitrate anion as a byproduct of the reduction of silver nitrate with a suspension of copper powder in acetonitrile. [4] [ Cu(CH 3 CN) 4]PF 6 is generally produced by the addition of HPF 6 to a suspension of copper(I) oxide in acetonitrile: [5]
Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate is an organoruthenium compound with the formula [(C 5 H 5)Ru(NCCH 3) 3]PF 6, abbreviated [CpRu(NCMe) 3]PF 6.It is a yellow-brown solid that is soluble in polar organic solvents.
Solvent degreasing is a process used to prepare a part for further operations such as electroplating or painting. Typically it uses petroleum , chlorine , dry ice or alcohol based solvents to dissolve the machining fluids and other contaminants that might be on the part.
For S N 1 reactions the solvent's ability to stabilize the intermediate carbocation is of direct importance to its viability as a suitable solvent. The ability of polar solvents to increase the rate of S N 1 reactions is a result of the polar solvent's solvating the reactant intermediate species, i.e., the carbocation, thereby decreasing the ...
A rotary evaporator [1] (rotovap) is a device used in chemical laboratories for the efficient and gentle removal of solvents from samples by evaporation.When referenced in the chemistry research literature, description of the use of this technique and equipment may include the phrase "rotary evaporator", though use is often rather signaled by other language (e.g., "the sample was evaporated ...
The removal method is controlled by the type of penetrant used. Water-washable, solvent-removable, lipophilic post-emulsifiable, or hydrophilic post-emulsifiable are the common choices. Emulsifiers represent the highest sensitivity level, and chemically interact with the oily penetrant to make it removable with a water spray.